ABSTRACT
Organolead trihalide perovskite solar cells have shown success as light absorbers in photovoltaic cells due to their efficiency increasing from 3.5% to over 20% within only five years. However, pinhole formation and incomplete coverage of solution-processed perovskite film results in increased current leakage, reducing efficiency. Hence the surface morphology of perovskite film is important for high performance of perovskite solar cells. Here the morphology is carefully controlled by varying processing conditions, perovskite films were prepared using two different lead sources: lead acetate (Pb(OAc)2) and lead iodide (PbI2), with methylammonium iodide (CH3NH3I) as the source material. The structural, optical and absorbance properties of the perovskite films varied with the lead sources used, perovskite from a Pb(OAc)2.3H2O source annealed at 90oC gave the best structure compared to Pb(OAc)2.3H2O annealed at 80oC and anhydrous Pb(OAc)2 annealed at 90oC. The perovskite film from the PbI2 source did not have smooth film, pinholes were formed with low crystallinity, a small amount of Pb(OAc)2 (about 5% mol) was added to the PbI2 in the solution, this improved the film crystallinity. The perovskite film derived from lead acetate showed enhanced surface coverage with quality crystalline film.
Lilian, O (2021). Morphology Analysis Of Lead Iodide- And Lead Acetatebased Perovskite Layers For Solar Cell Application. Afribary. Retrieved from https://afribary.com/works/morphology-analysis-of-lead-iodide-and-lead-acetatebased-perovskite-layers-for-solar-cell-application
Lilian, Osawemwenze "Morphology Analysis Of Lead Iodide- And Lead Acetatebased Perovskite Layers For Solar Cell Application" Afribary. Afribary, 15 Apr. 2021, https://afribary.com/works/morphology-analysis-of-lead-iodide-and-lead-acetatebased-perovskite-layers-for-solar-cell-application. Accessed 24 Nov. 2024.
Lilian, Osawemwenze . "Morphology Analysis Of Lead Iodide- And Lead Acetatebased Perovskite Layers For Solar Cell Application". Afribary, Afribary, 15 Apr. 2021. Web. 24 Nov. 2024. < https://afribary.com/works/morphology-analysis-of-lead-iodide-and-lead-acetatebased-perovskite-layers-for-solar-cell-application >.
Lilian, Osawemwenze . "Morphology Analysis Of Lead Iodide- And Lead Acetatebased Perovskite Layers For Solar Cell Application" Afribary (2021). Accessed November 24, 2024. https://afribary.com/works/morphology-analysis-of-lead-iodide-and-lead-acetatebased-perovskite-layers-for-solar-cell-application