This study examined the optimization of the transesterification reaction of sesame methyl esters (SMEs) with trimethylolpropane (TMP) to synthesise sesame biolubricant (SBL). Response surface methodology (RSM) using central composite design (CCD) was employed for the experimental design. Effects of temperature, mole ratio and reaction time on the yield of SBL were evaluated. The predicted yield after process optimization was found to agree satisfactorily with the experimental value. The o...
Jatropha curcas seed oil was studied for the synthesis of trimethylolpropane based biolube basestock via chemical transesterification of Jatropha methylester with trimethylolpropane (TMP) using calcium hydroxide catalyst. Reactions temperatures ranged between 80 and 160 C and methyl esters to TMP mole ratios ranged between 3:1 and 7:1. Product analysis, ester groups and physio-chemical properties were obtained by gas chromatography, Fourier transform infrared spectroscopy and American...
Synthesis of polyol ester as a novel biodegradable base stock from sesame seed oil for lubricant production was conducted via chemical transesterification of sesame methylester with trimethylolpropane (TMP) using calcium hydroxide catalyst. The reactions were carried out under varying temperatures (80 C160 C) and methyl esters to TMP mole ratios (3:1 to 7:1). Product’s analysis was performed using gas chromatography. Product’s physicochemical characteristics determined using ASTM met...
