Barium Titanate via Thermal Decomposition of Ba,Tiprecursor Complexes: The Nature of the Intermediate Phases

Solid State Sciences 9 (2007) 21, doi:10.1016/j.solidstatesciences.2006.09.004,

Abstract::

The thermal decomposition of Ba,Ti-precursor complexes, containing organic ligands and suitable for the single-source preparation of nanocrystalline BaTiO3, leads firstly to the segregation of specific Ba-rich and Ti-rich phases. Quantitative electron energy loss
spectroscopy and powder X-ray diffraction data indicated that the (i) Ba-rich phase is a BaOstabilised variant of the calcite-type high temperature modification of BaCO3 and (ii) Ti-rich phases are represented by low crystalline barium titanates with the general Ba:Ti ratio close to 1:4. The subsequent solid state reaction between these phases results then in the formation of BaTiO3.

Subscribe to access this work and thousands more
Overall Rating

0

5 Star
(0)
4 Star
(0)
3 Star
(0)
2 Star
(0)
1 Star
(0)
APA

Koferstein, R., Ischenko, V , Pippel, E , Abicht, H & Woltersdorf, J (2021). Barium Titanate via Thermal Decomposition of Ba,Tiprecursor Complexes: The Nature of the Intermediate Phases. Afribary. Retrieved from https://afribary.com/works/barium-titanate-via-thermal-decomposition-of-ba-tiprecursor-complexes-the-nature-of-the-intermediate-phases

MLA 8th

Koferstein, Roberto, et. al. "Barium Titanate via Thermal Decomposition of Ba,Tiprecursor Complexes: The Nature of the Intermediate Phases" Afribary. Afribary, 14 Jul. 2021, https://afribary.com/works/barium-titanate-via-thermal-decomposition-of-ba-tiprecursor-complexes-the-nature-of-the-intermediate-phases. Accessed 25 Apr. 2024.

MLA7

Koferstein, Roberto, Vladislav Ischenko , Eckhard Pippel , Hans-Peter Abicht and Jörg Woltersdorf . "Barium Titanate via Thermal Decomposition of Ba,Tiprecursor Complexes: The Nature of the Intermediate Phases". Afribary, Afribary, 14 Jul. 2021. Web. 25 Apr. 2024. < https://afribary.com/works/barium-titanate-via-thermal-decomposition-of-ba-tiprecursor-complexes-the-nature-of-the-intermediate-phases >.

Chicago

Koferstein, Roberto, Vladislav Ischenko , Eckhard Pippel , Hans-Peter Abicht and Jörg Woltersdorf . "Barium Titanate via Thermal Decomposition of Ba,Tiprecursor Complexes: The Nature of the Intermediate Phases" Afribary (2021). Accessed April 25, 2024. https://afribary.com/works/barium-titanate-via-thermal-decomposition-of-ba-tiprecursor-complexes-the-nature-of-the-intermediate-phases