Effects of silver catalyst concentration in metal assisted chemical etching of silicon

A systematic investigation is performed to determine the effects of the concentration of silver on metal assisted chemical etching (MaCE) on nanostructure formation mechanisms on silicon as well as their resultant optical properties. Silver nitrate concentrations of 0.008M, 0.004M, 0.003M and 0.002M with hydrogen fluoride were used for the preparation of p-type silicon nanostructures. Experimentally it is observed that when the catalysis molarity concentration is decreased in the etching processes, it resulted in macro, micro and nanostructures from 140 to 60 nm, respectively over the concentrations investigated. A detailed investigation of the optical and structure provided insight into the physics of their formation. In addition, the results show the silicon nanostructures formed black silicon where in the visible region of the spectrum the reflectance dropped by an order of magnitude. The results indicate MaCE is a promising approach to the manufacturing of antireflection coatings on black silicon-based solar photovoltaic cells. MaCE is a simple and scalable approach to enhance the optical absorption of silicon and improve the overall efficiency of the solar cell without adding significantly to the complexity, capital expenditure or cost of production.