Solid State Sciences 9 (2007) 303, doi:10.1016/j.solidstatesciences.2007.02.003,
Abstract::
(Ba,Ti)-precursor complexes, important for the production of advanced BaTiO3 perovskitetype materials, undergo structural transformations and complex reactions during their thermal decomposition. Based on XRD phase analysis, combined with Rietveld refinement of crystal structure data, and on IR analysis, the intermediate formation of calcite-type BaCO3 is evidenced, which can be explained by the stabilization of this metastable modification in the form of an oxycarbonate phase down to room temperature. Two possible processes, leading to such an oxycarbonate, are discussed: (i) partial substitution of CO32−by O2−in the anionic
sublattice, and (ii) topotaxial formation of calcite-type structural domains of BaCO3 by templating with oxygen-deficient titanates, resulting in the oxide–carbonate intergrowth structures.
Koferstein, R., Ischenko, V , Woltersdorf, J , Pippel, E & Abicht, H (2021). Formation of Metastable Calcite-type Barium Carbonate During Low-temperature Decomposition of (Ba,Ti)- Precursor Complexes. Afribary. Retrieved from https://afribary.com/works/formation-of-metastable-calcite-type-barium-carbonate-during-low-temperature-decomposition-of-ba-ti-precursor-complexes
Koferstein, Roberto, et. al. "Formation of Metastable Calcite-type Barium Carbonate During Low-temperature Decomposition of (Ba,Ti)- Precursor Complexes" Afribary. Afribary, 14 Jul. 2021, https://afribary.com/works/formation-of-metastable-calcite-type-barium-carbonate-during-low-temperature-decomposition-of-ba-ti-precursor-complexes. Accessed 26 Apr. 2024.
Koferstein, Roberto, Vladislav Ischenko , Jörg Woltersdorf , Eckhard Pippel and Hans-Peter Abicht . "Formation of Metastable Calcite-type Barium Carbonate During Low-temperature Decomposition of (Ba,Ti)- Precursor Complexes". Afribary, Afribary, 14 Jul. 2021. Web. 26 Apr. 2024. < https://afribary.com/works/formation-of-metastable-calcite-type-barium-carbonate-during-low-temperature-decomposition-of-ba-ti-precursor-complexes >.
Koferstein, Roberto, Vladislav Ischenko , Jörg Woltersdorf , Eckhard Pippel and Hans-Peter Abicht . "Formation of Metastable Calcite-type Barium Carbonate During Low-temperature Decomposition of (Ba,Ti)- Precursor Complexes" Afribary (2021). Accessed April 26, 2024. https://afribary.com/works/formation-of-metastable-calcite-type-barium-carbonate-during-low-temperature-decomposition-of-ba-ti-precursor-complexes