Distribution Of Heavy Metals In Cocoa Farm Soils In The Western Region Of Ghana

Western Region is the largest cocoa producer in Ghana. Cocoa farmlands have over the past decades received heavy doses of agrochemical application to boost cocoa production. These agrochemicals, however, may contain heavy metals and it is therefore likely that the metals may have accumulated in the soils. Evaluating the total concentrations and understanding the distribution characteristics of heavy metals in cocoa growing soils can aid environmental managers and even help regulate the rate of agrochemical application. A study was therefore, carried out on some selected soils of major cocoa growing areas in Western Region of Ghana to determine the levels of cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn) in the soils and also to determine some of the soil factors that control the distribution of the heavy metals in the soil. Eight soils (two Haplic Luvisols, three Ferric Acrisols, one Haplic Ferrasol and two Dystric Fluvisols) and their accompanying pristine soils as control were taken from adjacent natural forests sampled at depths of 0 – 10 cm, 10 – 30 cm, 30 – 50 cm, 50 – 80 cm and 80 – 100 cm. These soils were analysed for their particle size distribution, pH, organic carbon, cation exchange capacity, exchangeable bases, and total and bio-available Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn. The study indicated that the ΔpH which is pHKCl – pHH2O were all negative indicating that the soils generally had net negative charges on their colloidal surface. For all soils, clay content and pH increased with depth indicating co-migration of the two soil parameters whilst total organic carbon content decreased with depth. Cation exchange capacity, however, did not show any clear pattern with depth in the soils. The average abundance of heavy metals determined in these soils decreased as follows: Fe > Mn > Cr > Zn > Cu > Cd > Pb > Ni. The soils had low metal contents, less than or within the range of concentration for non-polluted soils and for European norms. However, total concentrations of Cd, Cu, Cr and Pb in the surface soils (0 – 10 cm) exceeded the thresholds for atmospheric fallout concentrations in top soil to 20 cm depth indicative of anthropogenic contamination. The lowest heavy metal contents were observed in the Haplic Luvisols while the highest metal loadings were in the Haplic Ferrasols and the Dystric Fluvisols. Depth function plots, ANOVA and correlation analyses indicated that clay influenced the distribution of Cr, Cu, Fe, Ni and Zn in the soils. Clay and total organic carbon controlled Cd distribution while pH and clay were associated with the distribution of Mn. Thus, clay had the most pronounce effect on the distribution of the metals in the soils. Accumulation-depletion ratios, enrichment factors and principal component analysis indicated that the distribution of Cd, Cu, Mn and Pb in the soils highlighted an anthropogenic pollution, most probably, from agrochemical inputs and/or from atmospheric deposition. Iron and Ni distributions were associated with lithogenic origin whereas Zn and Cr distribution were related to both anthropogenic and lithogenic contributions.