ABSTRACT This dissertation investigated the substitution of Kaolin with Coal Fly Ash (CFA) as raw material for the manufacture of cement. The research sought to establish the optimum quantity of CFA, Sand and Limestone required to produce a cement that had improved early day strength and latter strengths of cement due to substitution of kaolin with CFA. This was a novel and creative research where a total of twenty experiments formulated from the central composite design were carried out to ...
ABSTRACT Graphene nanoribbons (GNRs), titanium dioxide (TiO2), and their composites Graphene nanoribbons/titanium dioxide (GNRs/TiO2) were employed towards the simultaneous detection of nevirapine (NVP) and glucose (GLC). The nanomaterials were characterized Fourier-transform infrared spectroscopy (FTIR), UV-vis and thermogravimetric analysis (TGA), cyclic voltammetry, electrochemical impedance spectroscopy, linear sweep voltammetry, differential pulse voltammetry, and chronoamperometry were ...
BSTRACT Phytosynthesis of TiO2 NPs from Ximenia Caffra leaf extract and their application in poultry feeds as an antibacterial agent was done. Reaction time and pH effect for the synthesis of TiO2 NPs were optimized using a single factor method. A Central Composite Design (CCD) was used to determine the effect of linear factors (titanium tetrachloride concentration, temperature and leaf extract volume) and their interactions on the synthesis of TiO2 NPs. A total of twenty experiments formulat...
ABSTRACT A new simple novel electrochemical sensing platform based onelectrodeposition ofnano zinc oxide ontomultiwalled carbon nanotubes modified glassy carbon electrode was constructed. The modified electrode was characterized by cyclic voltammetry and electrochemical impedance in a redox probe.The electrode surface area after modification was 0.15 cm2, which was twice large that of a bare glassy carbon electrode. The new fabricated sensor was applied for individual and simultaneous determi...
ABSTRACT An electrochemical sensor based on polyaniline cobalt phtahlocyanito doped with cobalt oxide nanoparticles was developed for the electrocatalytic oxidation of amitrole.FTIR, Electrochemical impedance spectroscopy (EIS) and Bode plots were used in the characterization of the synthesized modifiers CoTCPc, PANI, Co2O3NPs and to ascertain the chemical linkage between CoTCPc and PANI while cyclic voltammetry, linear sweep, chronoamperometry and differential pulse voltammetry were used to ...
ABSTRACT An electrochemical sensor based on nickel tetraamine phthalocyanine and nitrogen doped grapheme oxide (NITAPC-NDGONS (mix)) nanoparticles was developed for the simultaneous electrocatalytic oxidation of vanillin and ascorbic acid. FTIR (Fourier Transimition Infrared), electrochemical impedance spectroscopy (EIS) and Bode plots were used in the characterization of the synthesized modifiers (NITAPC), (GONS-NITAPC) and NITAPC-NDGONS (mix)). Cyclic voltammetry, linear sweep, chronoampero...
ABSTRACT Azo dyes have become an immerging and difficult pollutant to the environment. Industrial activities have resulted in disposal of these toxic dyes in effluent and among them is methyl orange (MO) dye. Proper effluent treatment schemes have become a necessity so as to be able to reduce the potential toxicity issues regarding plant and animal life due to the rise in demand for clean and safe water. Several methods have been applied for the removal and degradation of MO dye but have prov...
ABSTRACT A novel maize tassel-ethyl acrylate biopolymer embedded magneticnanohybrid(MTEA-MN)was designed for the adsorption of Cd (II) in batch experiments.Copolymerization parameters such as solvent amount, initiator concentration, monomer concentration, temperature and reaction time on grafting percentage were optimized.Characterization of the adsorbent was byFourier transform infrared spectroscopy (FTIR). The effect of pH, contact time, initial concentration and adsorbent dosage and their ...
ABSTRACT Biodiesel, defined as the monoalkyl esters of vegetable oils and animal fats, is becoming prominent among alternatives to conventional petro-diesel due to economic, environmental and social factors. Transesterification is the most preferred method of biodiesel production. Knowledge of transesterification reaction kinetic enables prediction of the extent of the chemical reaction (or the conversion) at any time under particular conditions. It is also essential in the optimization of op...
ABSTRACT Transient compressible natural gas flow through a pipeline was studied by the use of a finite volume method in 2D axisymmetric cylindrical coordinates. To account for turbulence within the pipeline system, the standard turbulence model was simulated together with the Navier Stokes System of equations via the Reynolds-Averaged method. The equation of state employed was the SoaveRedlich-Kwong equation. Implicit discretization was used for the temporal terms, wherea...
ABSTRACT Background: Malaria is a common and life-threatening disease in Ghana. Malaria infection has been implicated in lipid and glucocorticoid imbalances among children. Cortisol-induced stresses and parasitaemia may affect brain development and risk of cardiovascular disorders among children. Aim: To investigate the impact malaria has on lipids and glucocorticoids in children. . Method: A comparative cross-sectional study using random sampling method was used in this study conducted betwe...
ABSTRACT Mature and ripe cashew fruits were harvested, washed and the apples separated from the nuts. The apples were crushed and the juice extracted, sieved and treated with potassium metabisulphite, to check the activities of undesireable microorganisms, before fermentation. A 3-spatula full of true wine yeast, Saccharomyces cerevisiae var. ellipsoideus, was rehydrated and inoculated into a 2.5-liter part of the juice and allowed for 5 days in a room temperature of 32.50C to ferment. After...
Abstract The CO2–hydrocarbons systems is common in oil and gas industry as a geological fluid. CO2 plays a vital role in biological processes namely photosynthesis, respiration, and actively participates in the carbon cycle. However, the time gradient of carbon dioxide concentration in the atmosphere has become a major global concern. The environmental challenges associated with the control and management of anthropogenic emissions of greenhouse gases have been the focal point of soci...
This research presents the effect of lye on the kinetics and quality of local soaps. To achieve this, 40ml of 10 percent lye (palm bunch, coconut shell and synthetic sodium hydroxide) reacted with 60ml of oil (palm oil and palm kernel oil) in a batch system, under conditions as, constant temperature (50 degree celcius) and constant stirring (100 rpm). Variation in saponification value and free fatty acid was monitored with time, that is, at intervals of 2mins. It was noticed that as time incr...