Chemistry Research Papers/Topics

Quantitative assessment of static versus dynamic environmental pollution risk from lead pollution at shooting ranges

Abstract: Lead pollution of soil arising from use of leaded ammunition in shooting ranges has received considerable attention from researchers, scientists, policy makers and legislatures. This is due to the adverse health effects associated with exposure to Pb. Eight military shooting ranges found in Botswana were used in this research project. All the eight shooting range soils were polluted with Pb with total Pb concentrations in the range 13-38 386 mg/kg. TAB shooting range soils acc...

Comparison of CaO-NPs and chicken egg shell derived CaO for the production of biodiesel from Schinziophyton rautanenii (Mongongo) nut oil

Abstract: The ever-increasing population growth and economic developments have led to a demand for energy. Therefore, this has resulted in a depletion and ever rising prices of petroleum diesel, hence increasing environmental degradation. These complications have motivated this study for the search of an alternative eco-friendly and renewable source of energy such as biodiesel. Biodiesel has been found to be a potential alternative fuel for diesel. It has the potential to solve the energ...

Synthesis, characterization of nitro or amino substituted pyridyl ligands bridged by an ester or ether bond, and their antibacterial assessment against drug resistant bacteria

Abstract: A series of ester and ether bridged compounds bearing the nitro and amino moieties were synthesized and characterized, in order to assess their ability to potentially serve as antibacterial agents against drug resistant bacteria. All the compounds were obtained at considerable yields while characterization techniques confirmed their successful synthesis. Furthermore, their antimicrobial assessments showed that all the compounds exhibited antibacterial activity against the Gram-nega...

Synthesis of bismuth oxyhalide (BiOBrz I (1-z)) solid solutions for photodegradation of methylene dye

Abstract: The removal of textile wastes is a priority due to their mutagenic and carcinogenic properties. In this study, bismuth oxyhalide was used in the removal of methylene blue (MB) which is a textile waste. The main objective of this study was to develop and investigate the applicability of a bismuth oxyhalide (BiOBr zI (1-z)) solid solutions in the photodegradation of MB under solar and ultraviolet (UV) light irradiation. Methods: Bismuth oxyhalide (BiOBr zI (1-z)) (0 ≤ z ≤ 1) mate...

Crystal Structure of Pyridin-4-ylmethyl 4-Nitrobenzoate, C13H10N2O4

Abstract: The structure of pyridin-4-ylmethyl 4-nitrobenzoate was determined by the single-crystal X-ray diffraction method. The compound crystallized in a monoclinic system, P21/n, and the unit cell parameters are, a = 9.981(2), b = 12.347(3), c = 10.161(3)Å, β = 101.450(9), Z = 4, V = 1227.3(5)Å3. The crystal structure was solved by intrinsic phasing and refined to final values of R1 = 0.0451 and wR2 = 0.1393

Thermo-fluidic significance of non Newtonian fluid with hybrid nanostructures

Abstract: The main purpose of this investigation is to analyze the flow and heat transfer behavior of a non Newtonian fluid (Oldroyd B fluid) with hybrid nanostructure subject to externally inclined magnetic field. Cattaneo Christov heat flux model is incorporated in the energy equation. Non linear thermal radiation and viscous dissipation mechanisms are considered. Shooting technique is implemented to accomplish the numerical solution. The outcomes of the numerical computations are discusse...

Antibacterial activity of 2-Picolyl-polypyridyl-based Ruthenium (II/III) complexes on non-drug-resistant and drug-resistant bacteria

Abstract: A new hexadentate 2-picolyl-polypyridyl-based ligand (4, 4’-(butane-1, 4-diylbis(oxy))bis(N, N-bis(pyridin-2-ylmethyl)aniline)) (2BUT) (1) and its corresponding Ru(II/III) complexes were synthesized and characterized, followed by assessment of their possible bioactive properties towards drug-resistant and non-drug-resistant bacteria. Spectroscopic characterization of the ligand was done using proton NMR, FTIR, and ESI-MS, which showed that the ligand was successfully synthesized....

An innovative microwave-assisted one-step green synthetic approach of biowaste derived fluorescent carbon-dot invisible ink for currency anti-counterfeiting applications

Abstract: The quest for the design and synthesis of carbon dots with anti-counterfeit properties that are derived via green, environmentally friendly and economical procedures is a continuous process. Carbon dots (C-dots) derived from biowaste are cheap to synthesize, possess good photo-stabilityand high synthetic yield, making them applicable in the anti-counterfeiting of currency. Herein, we report a novel eco-friendly, cheaper, and faster method for the synthesis of carbon dots with stron...

Mineralogy and geochemistry of the Ngaoundaba Crater Lake sediments, northern Cameroon: implications for provenance and trace metals status

Abstract: This study was conducted on the Ngaoundaba Crater Lake sediments to infer provenance, weathering conditions, organic matter accumulation, and trace metal concentrations. Ngaoundaba Lake sediments were collected using a manual core sampler at 5 to 8 m water depth. Two sediment cores from the littoral and center of the lake were analyzed for grain size distribution, water content (WC), organic matter content, mineralogy, and major and trace element concentrations. The Ngaoundaba sedi...

CONCENTRATION OF NUTRIENTS PRESENT IN FRESH AND ROASTED BUSH MEAT (GRASS CUTTER) (Thryonomys swinderianus) Victor-Osanyinlusi Remi1

Bush meat (Grass cutter) is one of the best natural meats with lots of nutritional advantages. The increase in consumption of bush meat serves as alternative which bridges the gap of the inadequacy of animal protein and other nutrition. The grass cutter (Thryonomys swinderianus) meat samples used in this research were collected from Emure Owo market, in Owo local government of Ondo state, Nigeria. The hairy skin of the fresh lifeless grass cutter was removed using hot water. The grass cutter ...

CONCENTRATION OF NUTRIENTS PRESENT IN FRESH AND ROASTED BUSH MEAT (GRASS CUTTER) (THRYONOMYS SWIDERIANUS)

Bush meat (Grass cutter) is one of the best natural meats with lots of nutritional advantages. The increase in consumption of bush meat serves as alternative which bridges the gap of the inadequacy of animal protein and other nutrition. The grass cutter (Thryonomys swinderianus) meat samples used in this research were collected from Emure Owo market, in Owo local government of Ondo state, Nigeria. The hairy skin of the fresh lifeless grass cutter was removed using hot water. The grass cutter ...

Cannabis sativa seed flour

  Abstract The hemp (Cannabis sativa) used for this work were obtained in a farm at Ogbese in Owo Local Government of Ondo State Nigeria. They were prepared for use by decoating, sun drying and milling. The milled sample were subdivided into two portions, one portion was defatted and named as defatted sample using normal hexane while the other portion was left raw. The samples were powdered in willey mill 60 mesh sizes and stored in screw cap bottle at room temperature for further analysis...

Biochemical Characteristics of the Hemp (Cannabis sativa) Seed Oil

Abstract The Cannabis sativa seed (India hemp) used for this work were obtained in a farm land at Ogbese in Owo Local Government Area of Ondo State Nigeria. The seed were prepared for use by decorating, and milling and sun drying. A soxhlet 0.01%), acid value (9.75±0.025), saponification value (2.65±0.15 mg/g/KOH), peroxide value (85±0.01 mg/kg), iodine value (110.00±0.25 wij) and the yield percentage is 35/05% respectively. The extractor was used and hexane was used as solvent, which wa...

The effect of various drying methods on the nutritional composition of Lycopersicum esculentum and Abelmoschus esculentus L.

Abstract Food drying is one of the methods for preserving perishable foods for long periods of time. The nutritional composition of tomato (Lycopersicum esculentus) and okra (Abelmoschus esculentum) was investigated using the commonly available drying methods (sun, oven, and solar drying). The nutritional compositions of these food crops were determined after they have been dried using various drying methods and milled to pass through mesh size. The moisture content of these food samples wa...

Comparative study on the Effect of boiling on the nutritional composition of garden egg solanum melogena

  Abstract Garden egg is a plant with edible fruit and its potential as a medicinal fruit have also been investigated. Extract has been suggested to have effects that could be therapeutic and nutritional. Analyses were carried out to determine the proximate and phytochemical constituents of both processed and raw indigenous Africa eggplant (Solanum macrocarpon and solanum aethiopicum). Proximate analysis of process and raw solanum macrocarpon (WBA) per (100%) showed: 75.13% moisture, 3.50% ...


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