Historically, the design of hybrid solar photovoltaic thermal (PVT) systems has focused on cooling crystalline silicon (c-Si)-based photovoltaic (PV) devices to avoid temperature-related losses. This approach neglects the associated performance losses in the thermal system and leads to a decrease in the overall exergy of the system. Consequently, this paper explores the use of hydrogenated amorphous silicon (a-Si:H) as an absorber material for PVT in an effort to maintain higher and more favourable operating temperatures for the thermal system. Amorphous silicon not only has a smaller temperature coefficient than c-Si, but also can display improved PV performance over extended periods of higher temperatures by annealing out defect states from the Staebler-Wronski effect. In order to determine the potential improvements in a-Si:H PV performance associated with increased thicknesses of the i-layers made possible by higher operating temperatures, a-Si:H PV cells were tested under 1 sun illumination (AM1.5) at temperatures of 25oC (STC), 50oC (representative PV operating conditions), and 90oC (representative PVT operating conditions). PV cells with an i-layer thicknesses of 420, 630 and 840 nm were evaluated at each temperature. Results show that operating a-Si:H-based PV at 90oC, with thicker i-layers than the cells currently used in commercial production, provided a greater power output compared to the thinner cells operating at either PV or PVT operating temperatures. These results indicate that incorporating a-Si:H as the absorber material in a PVT system can improve the thermal performance, while simultaneously improving the electrical performance of a-Si:H-based PV.
Pearce, J. (2019). The Effect of Hybrid Photovoltaic Thermal Device Operating Conditions on Intrinsic Layer Thickness Optimization of Hydrogenated Amorphous Silicon Solar Cells. Afribary. Retrieved from https://afribary.com/works/the-effect-of-hybrid-photovoltaic-thermal-device-operating-conditions-on-intrinsic-layer-thickness-optimization-of-hydrogenated-amorphous-silicon-solar-cells
Pearce, Joshua "The Effect of Hybrid Photovoltaic Thermal Device Operating Conditions on Intrinsic Layer Thickness Optimization of Hydrogenated Amorphous Silicon Solar Cells" Afribary. Afribary, 22 Apr. 2019, https://afribary.com/works/the-effect-of-hybrid-photovoltaic-thermal-device-operating-conditions-on-intrinsic-layer-thickness-optimization-of-hydrogenated-amorphous-silicon-solar-cells. Accessed 26 Nov. 2024.
Pearce, Joshua . "The Effect of Hybrid Photovoltaic Thermal Device Operating Conditions on Intrinsic Layer Thickness Optimization of Hydrogenated Amorphous Silicon Solar Cells". Afribary, Afribary, 22 Apr. 2019. Web. 26 Nov. 2024. < https://afribary.com/works/the-effect-of-hybrid-photovoltaic-thermal-device-operating-conditions-on-intrinsic-layer-thickness-optimization-of-hydrogenated-amorphous-silicon-solar-cells >.
Pearce, Joshua . "The Effect of Hybrid Photovoltaic Thermal Device Operating Conditions on Intrinsic Layer Thickness Optimization of Hydrogenated Amorphous Silicon Solar Cells" Afribary (2019). Accessed November 26, 2024. https://afribary.com/works/the-effect-of-hybrid-photovoltaic-thermal-device-operating-conditions-on-intrinsic-layer-thickness-optimization-of-hydrogenated-amorphous-silicon-solar-cells