The rate of reaction defines as the concentration of reactant or product, consumed or produced within a given time frame. Changing one of the variables could lead to a differing rates of reaction speeds.
ABSTRACT In this study, a series of N-pyridin-3-yl substituted [phenylsulphonamido] acetamide has been synthesized. The reaction of phenylsulphonyl chloride with various amino acids in basic medium yielded phenylsulphonamido alkanoic acid which, on chlorination with thionyl chloride, gave acid chloride derivatives of phenylsulphonamido alkanoic acid in situ. The acid chloride derivatives on condensation with 3-aminopyridine gave corresponding acetamide in good to excellent yield. The compoun...
ABSTRACT Five different filling stations (Station A, Station B, Station C, Station D and Station E) were analyzed for Total Petroleum Hydrocarbons and heavy metals concentration using Gas chromatography–mass spectrometry and atomic absorption spectrophotometer respectively. The result of the analysis obtained indicated that the percentage range of Total Petroleum Hydrocarbons (TPH) in soil is from 0.8061-34.3103%, respectively. Furthermore, the percentage range of underground water are from...
ABSTRACT The determination of some selected organochlorine pesticide residues in some vegetables grown within Gwagwalada Area Council were carried out using Gas Chromatography-Mass Spectrometric Technique (GC/MS). Lindane, Dieldrin, Endosulfan and Heptachlor were determined in Telfairia occidentalis, Amaranthus hybridus and Talinum triangulare obtained from some locations within Gwgwalada Area Council between the months of May and June, 2015. The pesticides were extracted by the method o...
Abstract Development of improved methods for the synthesis of copper nanoparticles is of high priority for the advancement of material science and technology. Herein, starch-protected zero-valent copper (Cu) nanoparticles have been successfully synthesized by a novel facile route. The method is based on the chemical reduction in aqueous copper salt using ascorbic acid as reducing agent at low temperature (80 °C). X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spe...
CHAPTER ONE 1.0 INTRODUCTION Bioactive plants are commonly used by traditional healers or in folklore medicines for the relief of pain or some alignments. This act of medication has made some plant families popular (Heinrich 2000; Kuete et al., 2006).The acceptance of traditional medicine as an alternative form of health care has assisted scientists in elevating these claims, by studying the chemical composition and biological potential (Bisignano et al., 1996; Hammer et al., 1999). This ...
Sorption and desorption of rifampicin was assessed on three different soil. Sorption mechanism was studied in terms of equilibrium and kinetics at different pH. Linear, Freundlich and Langmuir isotherm models were adopted to study the isotherm. The experimental data were best described by pseudo-second order kinetics (R2 = 1.00). It was observed that rifampicin absorbs better on soil with lowest organic carbon content. Sorption was observed to increase with decrease in aqueous pH and increase...
ABSTRACT The production of potassium salt K2SO4 from unripe plantain agricultural waste was carried out. The sample randomly sourced from canteens located in Owerri West, Imo State. From the result of analysis carried out on the peels was found to contain highest level of K 2.55 ± 1.54 mg/g. other mineral component found were Na 159 ± 1.3 mg/g, Ca 101 ± 0.95 mg/g, Mg 75 ± 0.55 mg/g, Fe 5.8 ± 0.06 mg/g, P 36 ± 1.65. The yield of potassium sulphate, the target of this work is 40.5%...
ABSTRACT The proximate compositions of African elemi nut were investigated by analyzing the moisture content, crude fat, ash content, crude fibre, crude protein and total carbohydrates in the nut. The associations of official analytical chemist (AOAC, 2000) methods were used. The values obtained from the proximate analysis were; moisture content (28.79%), ash (3.41%), crude fiber (2.84%), fat (30.42%), protein (8.40%), carbohydrate (26.14%). The GC-MS characterization revealed that the plant ...
ABSTRACT This research work is on the preliminary determination of active components in bitter leaf root (vernonia amygdalina) in the treatment of diabetes. Deficiency of hormone (insulin) causes diabetes mellitus, a disease due to too much of sugar being present in the blood. This is because without insulin in the body, the result is that sugar is extracted in the urine. Consequently, fat and proteins are readily converted to carbohydrates and finally, glucose eventually. The body reserves ...
CHAPTER ONE 1.0 INTRODUCTION 1.1 NICKEL 1.1.1 Occurrence Nickel (Ni) is a metallic element,with atomic number 28; atomic weight 58.69. Is a metal, which belongs to group VIIIB of the periodic table. The most important oxidation state of nickel is +2, although the +3 and +4 oxidation states are also known (Tundermann et al., 2005). Nickel resembles iron, cobalt, and copper in its chemical properties. However, unlike cobalt and iron, it is normally only stable in aqueou...
Mechanochemical synthesis of [Cu(OOCCH3)2(THB)2] and the Mechanochemical synthesis of [Cu(OOCCH3)2(THB)2] were carried out, and a brown solid complexes obtained in both experiment was washed in ethanol respectively. The physical and instrumental characterisation of the complexes carried out revealed that the complexes obtained are the same
ABSTRACT Spectroscopic method was used to determine quantities of carotene and ascorbic acid in carrot, cucumber, eggplant and tomatoes. The result shows that carrot has higher concentration of carotene =0.1430, follow by eggplant = 0.6950 and tomatoes = 0.0368 and cucumber has the least concentration of carotene =0.0139. The result also show carrot has higher concentration of ascorbic acid 0.958×10-4 mol/d3 follow by tomatoes 0.944×10-4 mol/d3 and eggplant 0.943×10-4 mol/d3 cucumber 0.901...
ABSTRACT Lannea acida is a plant known to have various medicinal and therapeutic properties. The phytochemicals or secondary metabolites and antibacterial activity of its root and stem bark were studied in this research work. The phytochemical screening of the plant was carried out using standard methods of analysis and these investigations revealed the presence of bioactive components comprising flavonoids, alkaloids, saponins, steroids, terpenoids, gly...
ABSTRACT Roadside soil samples were obtained from Eka Street, Oron Road, Ikot Ekpene Road and Nwaniba Road within Uyo metropolis, Akwa Ibom State. Roadside soils were also obtained from Uwana Lane and used as Control. These samples and Control were analysed for the concentration of Cadmium (Cd), Nickel (Ni), Lead (Pb), Zinc (Zn) and Iron using Atomic Absorption Spectrophotometer (AAS) unicam 939 model. Results obtained indicated the following mean concentration (mg/kg) for metals in roadsi...