This study examined the optimization of the transesterification reaction of sesame methyl esters (SMEs) with trimethylolpropane (TMP) to synthesise sesame biolubricant (SBL). Response surface methodology (RSM) using central composite design (CCD) was employed for the experimental design. Effects of temperature, mole ratio and reaction time on the yield of SBL were evaluated. The predicted yield after process optimization was found to agree satisfactorily with the experimental value. The o...
Jatropha curcas seed oil was studied for the synthesis of trimethylolpropane based biolube basestock via chemical transesterification of Jatropha methylester with trimethylolpropane (TMP) using calcium hydroxide catalyst. Reactions temperatures ranged between 80 and 160 C and methyl esters to TMP mole ratios ranged between 3:1 and 7:1. Product analysis, ester groups and physio-chemical properties were obtained by gas chromatography, Fourier transform infrared spectroscopy and American...
Synthesis of polyol ester as a novel biodegradable base stock from sesame seed oil for lubricant production was conducted via chemical transesterification of sesame methylester with trimethylolpropane (TMP) using calcium hydroxide catalyst. The reactions were carried out under varying temperatures (80 C160 C) and methyl esters to TMP mole ratios (3:1 to 7:1). Product’s analysis was performed using gas chromatography. Product’s physicochemical characteristics determined using ASTM met...
Abstract Fluidized bed reactor is useful for heterogeneous (multi phase) reactions, separations, size enlargement, coating, and blending in chemical and pharmaceuticals industries. To develop a model and simulation of this reactor with advanced systems process engineering software (Aspen Plus). Aspen plus has the capability to simulate real factory performance, design improved plants, and intensify profitability in present plants. This modeling and simulation are applied Geldart B particle cl...
Indubitably the most challenging coronavirus (Covid-19) outbreak, caused by SARS-CoV-2. With the number of Covid-19 cases now approaching millions globally so, for controlling the current infection rate, we have come up with this innovation of virus repellent electric liquid vaporizer means by vaporization of the solution which is the in-liquid form by means of electricity, which will enable the infectious virus and bacteria to be less effective also it will sometime kill the virus in a small...
Abstract:Fluidized bed reactor is useful for heterogeneous (multiphase) reactions, separations, size enlargement, coating, and blending in chemical and pharmaceuticals industries. To develop a model and simulation of this reactor with advanced systems process engineering software (Aspen Plus). Aspen plus has the capability to simulate real factory performance, design improved plants, and intensify profitability in present plants. This modeling and simulation are applied Geldart B particle cla...
ABSTRACT The physical properties of CNSL extracted by pyrolysis was studied using standard procedures. The physical properties of the CNSL studied and results obtained compared with other extraction methods (hexane extracted and decarboxylated) from literature are moisture content 4.1%, (6.40%, 3.2%), specific gravity 0.943 (0.926, 0.926) viscosity 57cp (40cp, 358cp), pH 4.5 (4.5, 5.2) and the percent composition of the CNSL compared with those from literature are cardol 27% (30%, 31% (carda...
ABSTRACT In this study, the potential effects of animal derived organic manure (cow dung, poultry droppings), saw dust and NPK fertilizer on the bioremediation of petroleum hydrocarbon contaminated soil was investigated. The rate of biodegradation was studied for the period of 10 weeks under laboratory conditions. The biodegradation data were fitted to eight models, four of which are based on microbial growth rate and the other four based on order of reaction. Results obtained show that bior...
ABSTRACT Remediation of hydrocarbon polluted soil applying all existing techniques can be slow, expensive and requires close monitoring. Bioremediation and phytoremediation augmented bioremediation have been used to treat petroleum contaminated soil and even the difficult poly aromatic hydrocarbon polluted soil which takes longer time. What has not been studied was the effect of heavy metals present in petroleum which slows down the substrate degradation by microorganisms. After the primary ...
ABSTRACT The development of a Cathodic Protection System for a mild steel pipe using a magnesium anode was investigated. The pipe was externally coated with three layers of polykene tape wrapping and the soil resistivity was determined using the Wenner four pin method; a value of 2177Ωcm was obtained. The design parameters for the developed Cathodic Protection System were: total current of 0.0153mA; current density of 0.01mA/m 2 ; protection current of 0.0153mA; protection voltage of 0.95V...
ABSTRACT In this work, the operation and performance of a novel Separation Tray Column under Vertical and Tilt conditions is presented. The Tray Column used for the work is a Downcomerless liquid initiated and controlled Valve Tray with capacity to shut portions of the tray lacking liquid at any time. To evaluate the mass transfer performance of this column, an oxidation experiment was conducted at 300C and the percentage of Fe (II) oxidised to Fe (III) from contaminated water by air was cho...
ABSTRACT . The surface charge density (σo) of colloidal alpha-alumina suspended in various 1:1 electrolytes was measured using acid-base titration. An auto titrator capable of dispensing accurately 25 ± 0.1 µL of titrant was used. The pH and temperature in the titration cell were monitored using single-junction electrodes and platinum resistance thermometers, respectively. A constant supply of nitrogen gas in the cell was used to maintain inert conditions. The whole set-up was interfaced w...
ABSTRACT African Locust Bean (Parkia biglobosa) seeds known as ‘Iyere’ in Yoruba language were fermented aerobically and anaerobically at 40, 50, 60 and 70 °С for five days (120 hours) with the aid of two starter cultures - Bacillus Subtilis and Saccharomyces Cerevisiae to a vegetable protein based food condiment known as ‘Iru’. The Fermenter was fabricated with galvanized iron, thus getting rid of the unhygienic methods of producing it locally. Samples were taken every day (24 hour...
ABSTRACT Zeolites are important chemical materials used in chemical processes. The manufacture of the materials usually involves the use of expensive chemicals. This study involves the use of Elefun Nigerian Kaolin (ENK) as precursor material for the development of zeolite Y. The synthesis of zeolite Y was successful following a sequence: collection of raw kaolin clay from Elefun area of Ogun state, Nigeria; subjecting it to, calcination, partial dealumination and final hydrothermal syn...
ABSTRACT Converting the huge amount of waste cooking oils presently generated globally to biodiesel as complementary energy source to fossil fuel is one of the major routes to sustainable energy management. However, producing quality biodiesel at established optimum conditions, through a clean technology with favourable environmental implications is of greater importance. This research focused on achieving the latter through alkali catalysed trans-esterification process of biodiesel producti...