ABSTRACT A simple and sensitive spectrophotometric method for the determination of paracetamol was explored, using zirconium(IV) and vanadium(V) oxides. The method was based on the oxidation of paracetamol by zirconium(IV) and vanadium(V) in alkaline and acidic media respectively. The stoichiometric studies indicated a mole-ratio of 1:1 for the reactions of paracetamol with both zirconium(IV) and vanadium(V). Effects of other variables like pH, temperature and time were determined and showed...
ABSTRACT 3D as-built models have been utilized over the years as an aid to several engineering activities and there are conventional survey methods; e.g. Total Station ray method, photogrammetric technique etc., with which the data required for these models are generated. These methods have proven not to be optimal in capturing datasets required for the modeling of some complex engineering structures. The reasons for this been the intrusive nature of some of these methods and their point ra...
ABSTRACT The removal of Pb(II) ions from aqueous model solution using zeolite has been investigated under different operational parameters like heavy metal ion concentration, adsorbent amount and particle size. The zeolite used was synthesized and characterized using SEM and XRD analysis. The equilibrium adsorption capacity of zeolite used for lead removal were measured and the experimental data analyzed by means of Freundlich and Langmuir isotherm models. The adsorption efficiency of Zeolit...
ABSTRACT The synthesis of N-heteroaryl substituted benzene sulphonamides and evaluation of their biological activities are reported. Synthesis was achieved by the reaction of benzene sulphonyl chloride and substituted amino heterocycle in dry pyridine. The structures of synthesized compounds were assigned by spectroscopic methods. The eight (8) synthesized compounds were evaluated for antibacterial and antifungal activities. The results showed that some of the new compounds exhibited activit...
ABSTRACT Security is a very vital factor for human growth and development. It has also become a major recent issue in buildings and especially, school buildings. Ensuring security in buildings is a collective endeavour with each individual, government, organization, and community having its own role to play. The architect, who is the master builder, is chiefly responsible in ensuring that the built environment meets requirements of security. This report studied the various techniques of ach...
ABSTRACT The kinetics and mechanisms of the redox reactions of oxidant, m -adipato-di(N,N/ - bis(salicylidene)ethylenediaminatoiron(III),[(Fe-salen)2adi],hereafter denoted as Fe2adi, with the thiols L-cysteine (LSH), thiourea (USH), thioglycolicacid(GSH),2– mercaptobenzothiazole (BTSH) and benzylmercaptan (BSH) have been studied spectrophotometrically at 495 nm in aqueous perchloric acid, I=0.01mol dm-3 (NaClO4) and at 29 ± 1o C. The stoichiometry of 1:1 was obtained for Fe2adi – LSH, F...
ABSTRACT The synthesis of five mono- and five bis-alkynylated derivatives of quinoline-5,8-diones is reported. The intermediate 6,7-dibromoquinoline-5,8-dione was obtained by nitrosation of 8- hydroxyquinoline, followed by reduction and subsequent bromination and oxidation. The coupling reaction of 6,7-dibromoquinoline-5,8-dione via palladium-catalyzed Sonogashira cross-coupling gave the alkynylated products. The chemical structures of the products were confirmed using spectroscopic methods ...
Table of Contents CHAPTER ONE INTRODUCTION 1.1BACKGROUND OF THE STUDY The combined building materials are: 1.1.1 HISTORY OF KANO CITY 1.2 PROBLEM STATEMENT 1.3 RESEARCH QUESTIONS 1.4 AIM AND OBJECTIVES 1.5 SCOPE OF THE STUDY 1.6 SIGNIFICANCE OF THE STUDY 1.7 METHODS OF STUDY CHAPTER TWO LITERATURE REVIEW 2.1 DEVELOPMENT AND EVOLUTION OF BUILDING MATERIALS 2.2 INDIGENOUS BUILDING MATERIALS 2.2.1 Identified common indigenous building materials in Nigeria 2.2.2 Mud (tubali) 2.2.3 Pl...
ABSTRACT Production of carbon black from novel sources like spent automobile tyre, anthracite coal, furnace soot and graphite rod and subsequent use in the production of offset printing inks has been investigated. Carbon black from these sources were obtained by pyrolysis of shredded spent tyre and coal samples at 750-900o C in an electrical furnace, isolation of furnace carbon black and graphite rod from dry cell, drying and pulverization of the resulting samples. Acid demineralization of ...
Abstract The study area comprised Uburu and Okposi towns in Ohazara Local Government Area, Ebonyi state and it lies between latitudes 60 00’N and 60 05’N, and longitudes 70 44’E and 70 50’E. The area belongs to the saline hydrogeological groundwater basin of Albian Asu River Group in Cross River Basin. Three major outcrops of saline groundwater in the study area are: Umuchime- Uburu lake, Ivu-Ezizo and Amaechi-Okposi lakes. The saline lakes support long production of salts by rural ...
ABSTRACT Changes in precipitation characteristics have been identified to exert profound socio-economic consequences over West Africa. This study analysed climate model simulation and projections of precipitation changes over West Africa using the Norwegian Earth System Model (NorESM with Lat-Lon resolution of 1.89° by 2.5°). The skill of the model in reproducing the observed precipitation was evaluated for the present-day (1980-2005), its bias and relationship was determined using satellit...
ABSTRACT The improvement of the combustion properties of coal and biomass by blending and carbonization was investigated. Proximate and ultimate analysis of coal, sawdust, corn cob and their blends were carried out using ASTM methods. The proximate and ultimate analyses were repeated on the five blends after carbonization at 500o C for one hour. Ten mixtures of coal-sawdust and coal-corn cob blends were made into briquettes using starch binder. The calorific values of the samples were determi...
ABSTRACT The study sought to assess the solid waste disposal pattern of sellers in Mile One Market Port Harcourt in order to: identify the solid waste disposal habits of sellers, determine the frequency of clearing dumpsters from the market, determine accessibilityof waste dumpsters to market sellers and ascertain if the pattern of waste disposal significantly vary from different section of the markets.Data wereobtained throughinterviews, questionnaires and on the spot observation. A total of...
ABSTRACT In a bid to address the impact of slum development on the wetlands many organizations have developed mechanisms aimed at reducing on the rate of slum development but several measures still need to be put in place as well as elevate the lives of the people living in the slum areas for example the building of a better drainage system, provision of safe drinking water, sensitization on better sanitation practices thus creating a favorable living atmosphere. The main objective of this re...
Abstract This study has been carried out in Radiation and Isotopes Center of Khartoum and Khartoum hospital, it, s aim was to the assessment of the effect of radiation in Blood Components from Tc-99m/MDP Bone Scintigraphy, such as the effects in WBCs, RBCs, PLT, HCT, MCV, LYM and HGB in addition to geographical distribution of cancer and highlighting the most common cancer in Sudan. The study conducted on 50 patients (50) as 76% female and 24 % male with different ages that candidate to the b...