Abstract The Fischer-Tropsch synthesis (FTS) process, better known for its ability to produce synthetic fuel via the hydrogenation of CO, has shown potential to produce valuable chemicals when ammonia is added to the feed. In this work certain aspects of the pathway to the formation of N-containing compounds that form when NH3 is added during FTS, using mostly iron based catalysts is investigated. In addition, the effect this has on the FTS reaction itself is evaluated. To achieve this goal, ...
Abstract This work tests the hypothesis that nanoparticles of 75 at.% platinum (Pt) composition and anisotropic morphology, will outperform standard catalysts in (PEMFC) hydrogen fuel cells. A survey of the scientific literature on this topic is first presented. The synthetic strategies which were developed for the preparation of novel Pt-based binary (bimetallic) and ternary (trimetallic) nanoparticles, containing nickel (Ni), cobalt (Co) and/or vanadium (V), are then described. The synthes...
Abstract The advent of CubeSats has provided a platform for relatively low-budget programmes to realise space missions. In South Africa, Stellenbosch University and the Cape Peninsula University of Technology have impressive space programmes and have been involved in numerous successful satellite launches. A number of CubeSat projects are currently in progress and commercial-grade Attitude Determination and Control Systems (ADCS), and communications modules, are being developed by the respect...
Abstract Active object recognition provides a mechanism for selecting informative viewpoints to complete recognition tasks as quickly and accurately as possible. One can manipulate the position of the camera or the object of interest to obtain more useful information. This approach can improve the computational efficiency of the recognition task by only processing viewpoints selected based on the amount of relevant information they contain. Active object recognition methods are based around h...
Abstract The Microsoft Kinect sensor is a low cost RGB-D sensor. In this dissertation, its calibration is fully investigated and then these parameters are compared to the parameters given by Microsoft and OpenNI. The parameters found were found to be di_erent to those given by Microsoft and OpenNI therefore, every Kinect should be fully calibrated. The transformation from the raw data to a point cloud is also investigated. Then, the Hough transform is presented in its 2-dimensional form. The ...
Abstract The aim of this research was to develop an understanding of and measure the potential for sustainability in a South African urban water context. This was achieved through the use of a systems approach to develop and evaluate a composite index – the Sustainability Index for Integrated Urban Water Management (SIUWM) – based on a vision of what sustainable urban water management means to decision makers at selected local authorities around the country. The vision was expanded into ...
Abstract Within froth flotation, it is widely acknowledged that froth stability affects flotation performance. As a result, it is expected that through the effective management of froth stability, it would be possible to both control and optimise a flotation cell and bank. However, for this to be possible, the relationships between the operating conditions, froth stability behaviour and flotation performance attributes need to be well understood. In addition, froth stability would need to be ...
Abstract This body of work entailed the broad contrasting of two hydrocarbon fuel auto-ignition models formulated for the emulation of combustion dynamics in Homogeneous Charge Compression Ignition (HCCI) engines. The first (empirical) auto-ignition model was adapted from its previously published form, for HCCI engine model implementation. This model was then combined with an explicit, single zone, thermodynamic engine model in order to investigate combustion phasing control strategies over ...
Abstract Water is not only essential for maintaining life; it is a key component of sustainable social and economic development having links to, inter alia, health, “sense of place”, food production and industrial growth. Although progress has been made with regard to water supply, it is estimated that there are still 2.4 million people in South Africa without access to adequate water and sanitation services as defined by the United Nations (Statistics South Africa, 2008). It is possible...
Abstract This research forms part of an ongoing HCCI study at the SASOL Advanced Fuels Laboratory to investigate and understand engine configuration and fuel chemistry effects on combustion in HCCI engines. This project continues from a previous project where a small Progress Aero Works (PAW) 6.5cc high speed model diesel" aeroplane engine was found to operate in HCCI mode with surprising ease and exibility. A 25cc, four-stroke, single cylinder Honda GX25 engine, possessing 2-valves with an o...
ABSTRACT BIOLOGICAL SULPHATE REDUCTION USING PRIMARY SEWAGE SLUDGE AS ENERGY SOURCE IN AN UPFLOW ANAEROBIC SLUDGE BED REACTOR Since the economics of biological sulphate reduction (BSR) are driven by the economics of the organic carbon source, the BioSURE® process has been developed as a low-cost effective system where primary sewage sludge (PSS) is used as the energy source. This research investigates the use of PSS for BSR in an upflow anaerobic sludge bed (UASB) reactor in detail in ord...
ABSTRACT The effect of impurities on the precipitation behaviour of nickel powder produced by high-pressure hydrogen reduction was investigated in order to determine the factors responsible for the formation of powder with undesirable morphology. In nickel precipitation by hydrogen reduction, two product morphologies have been observed: the spherical, open powder (desirable) and the spherical, closing/closed powder (undesirable). Two major impurities were studied namely; a morphology modifie...
Blast loading of sandwich panels with thin-walled tube cores
Abstract A 3-phase Z-source inverter has been researched, designed, simulated, built and tested. The purpose of the inverter is to deliver 3-phase 400 VAC from a DC supply that can vary over a range of 20 to 70 Vdc. This is done with a Zsource inverter topology which is a single conversion method with no additional DC to DC boost converter. A novel DSP control algorithm allows the inverter to achieve the following: · Run Space Vector Pulse Width Modulation (SV-PWM) for maximum DC bus voltag...