Natural & Applied Sciences

Research Papers/Topics Natural & Applied Sciences

The effect of substituents on the stability and fragmentation of para benzoquinone molecular anion

Abstract: Quinones form a large group of organic compounds with various applications in industry, biological systems, and pharmacology. They can capture an electron with kinetic energy exceeding zero and keep it for a longer time. The principal structure responsible for electron capturing in quinones is the para-benzoquinone, PBQ. Several studies have been carried out on PBQ and its molecular anion, but less attention has been paid to its derivatives upon capturing an electron. As such,...

A surface photovoltage study of surface defects on Co-doped TiO2 thin films deposited by spray pyrolysis

Abstract: Surface photovoltage (SPV) spectroscopy is a powerful tool for studying electronic defects on semiconductor surfaces, at interfaces, and in bulk for a wide range of materials. Undoped and Cobalt-doped TiO 2 (CTO) thin films were deposited on Crystalline Silicon (c-Si) and Flourine doped Tin oxide (SnO 2 :F) substrates by chemical spray pyrolysis at a substrate temperature of 400 °C. The concentration of the Co dopant in the films was determined by Rutherford backscattering spectro...

Synthesis, characterization of nitro or amino substituted pyridyl ligands bridged by an ester or ether bond, and their antibacterial assessment against drug resistant bacteria

Abstract: A series of ester and ether bridged compounds bearing the nitro and amino moieties were synthesized and characterized, in order to assess their ability to potentially serve as antibacterial agents against drug resistant bacteria. All the compounds were obtained at considerable yields while characterization techniques confirmed their successful synthesis. Furthermore, their antimicrobial assessments showed that all the compounds exhibited antibacterial activity against the Gram-nega...

Approximating fixed points of the composition of two resolvent operators

Abstract: Let A and B be maximal monotone operators defined on a real Hilbert space H, and let Fix, (eqution found) and μ is a given positive number. [H. H. Bauschke, P. L. Combettes and S. Reich, The asymptotic behavior of the composition of two resolvents, Nonlinear Anal. 60 (2005), no. 2, 283-301] proved that any sequence (xn) generated by the iterative method, (eqution found) converges weakly to some point in Fix(JAμ JBμ). In this paper, we show that the modified method of alternating...

The type II Topp-Leone-G power series distribution with applications on bladder cancer

Abstract: Statistical distributions are important in modeling the real life of an item and therefore proper distributions that provide useful information for sound conclusions and decisions are needed. For that reason, the demand for developing new generalized distributions have become appropriate for data that have both monotonic and non-monotonic hazard rate functions. In this paper, we develop a new distribution called the Type IITopp-Leone-G Power Series (TIITLGPS) distribution by compou...

Effect of Cd precursor on structure and optical properties of spin coated Zn0:9Cd0:1O films for optoelectronics applications

Abstract: The development of transparent conducting oxide materials has gained an increased interest in the scientific community for developing efficient low cost optoelectronic devices. The effect of Cd precursor on structural and optical properties of sol-gel synthesized Zn0.9Cd0.1O nanostructured films has been studied by using XRD, AFM, optical absorption and emission spectroscopic techniques. X-ray diffraction confirms the hexagonal wurtzite crystal structure of the deposited films and ...

Hierarchical multilevel optimization with multiple-leaders multiple-followers setting and nonseparable objectives

Abstract: Hierarchical multilevel multi-leader multi-follower problems are non-cooperative decision problems in which multiple decision-makers of equal status in the upper-level and multiple decision makers of equal status are involved at each of the lower-levels of the hierarchy. Much of solution methods proposed so far on the topic are either model specific which may work only for a particular sub-class of problems or are based on some strong assumptions and only for two level cases. In th...

Multi-source reliable multicast routing with QoS constraints of NFV in edge computing

Abstract: Edge Computing (EC) allows processing to take place near the user, hence ensuring scalability and low latency. Network Function Virtualization (NFV) provides the significant convenience of network layout and reduces the service operation cost in EC and data center. Nowadays, the interests of the NFV layout focus on one-to-one communication, which is costly when applied to multicast or group services directly. Furthermore, many artificial intelligence applications and services of cl...

Loss-tolerant prepare and measure quantum key distribution protocol

Abstract: We propose a modified version of the Bennett–Brassard 1984 quantum key distribution protocol intended to tolerate losses, certain forms of noise, and the so-called photon number splitting attack. These are the issues facing the realization of practical quantum key distribution. The modified protocol is based on quantum non-demolition measure ments for systems using weak coherent pulses. Our scheme ensures that emissions cor responding to zero photon pulses, multi-photon pulses, a...

Long-range memory effects in a magnetized Hindmarsh-Rose neural network

Abstract: We consider a model network of diffusively coupled Hindmarsh-Rose neurons to study both analytically and numerically, long-range memory effects on the modulational instability phenomenon, chaotic, synchronous and chimera states within the network. The multiple scale method is used to reduce the generic model into a discrete nonlinear Schrödinger equation. The latter is explored in the linear stability analysis and the instability criterion along with the critical amplitude are der...

The burr-weibull power series class of distributions

Abstract: A new generalized class of distributions called the Burr-Weibull Power Series (BWPS) class of distributions is developed and explored. This class of distributions generalizes the Burr power series and Weibull power series classes of distributions, respectively. A special model of the BWPS class of distributions, the new Burr-Weibull Poisson (BWP) distribution is considered and some of its mathematical properties are obtained. The BWP distribution contains several new and well known...

Synthesis of bismuth oxyhalide (BiOBrz I (1-z)) solid solutions for photodegradation of methylene dye

Abstract: The removal of textile wastes is a priority due to their mutagenic and carcinogenic properties. In this study, bismuth oxyhalide was used in the removal of methylene blue (MB) which is a textile waste. The main objective of this study was to develop and investigate the applicability of a bismuth oxyhalide (BiOBr zI (1-z)) solid solutions in the photodegradation of MB under solar and ultraviolet (UV) light irradiation. Methods: Bismuth oxyhalide (BiOBr zI (1-z)) (0 ≤ z ≤ 1) mate...

The Topp Leone-G Power Series class of distributions with applications

Abstract: We present a new class of distributions called the Topp-Leone-G Power Series (TL-GPS) class of distributions. This model is obtained by compounding the Topp-Leone-G distribution with the power series distribution. Statistical prop erties of the TL-GPS class of distributions are obtained. Maximum likelihood estimates for the proposed model were obtained. A simulation study is carried out for the special case of Topp-Leone Log-Logistic Poisson distribution to assess the performance o...

Pollution status of shooting range soils from Cd, Cu, Mn, Ni and Zn found in ammunition

Abstract: Evaluation of concentration of heavy metals found in shooting range soil is important in assessing the pollution risk posed to biota. Soil samples from five shooting ranges found in Botswana were used in this study. All the five shooting ranges accumulated high concentration of Cu ranging from 67.4 ± 0.05 mg/kg to 1569 ± 13 mg/kg followed by Mn (25.9 ± 0.1–953.8 ± 2.8 mg/kg). Pollution risk indices were used to quantify the environmental pollution risk posed by the differ- en...

Relative gottlieb groups of embeddings between complex grassmannians

Abstract: Let Grk,n be the complex Grassmann manifold of k-linear subspaces in ℂn. We compute rational relative Gottlieb groups of the embedding i:Grk,n Grk,n+r and show that the G-sequence is exact if r≥kn-k.


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